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1 article(s) from Meng, Melissa

Oligonucleotide analogues with cationic backbone linkages

Melissa Meng and
Christian Ducho

Beilstein J. Org. Chem. 2018, 14, 1293–1308, doi:10.3762/bjoc.14.111

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Graphical Abstract

Figure 1: Biological action of single-stranded oligonucleotides (ON): antigene and antisense pathways.

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Figure 2: Selected examples 1–6 of nucleic acid modifications based on additionally attached positively charg...

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Figure 3: Oligonucleotide analogues with artificial cationic backbone linkages discussed in this review: amin...

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Scheme 1: Structure of Letsinger's modified deoxyadenosyl dinucleotide 11 and synthesis of cationic oligonucl...

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Figure 4: Artificial cationic backbone linkages 19 and 20 which are structurally related to aminoalkylated ph...

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Scheme 2: Bruice's synthesis of guanidinium-linked DNG oligomer 29 in the 5'→3' direction (Troc = 2,2,2-trich...

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Scheme 3: Bruice's synthesis of purine-containing guanidinium-linked DNG oligomer 36 in the 3'→5' direction (...

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Scheme 4: Bruice's synthesis of S-methylthiourea-linked DNmt oligomer 43.

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Figure 5: Structure of the natural product muraymycin A1 (44) and design concept of nucleosyl amino acid (NAA...

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Scheme 5: Retrosynthetic summary of Ducho's synthesis of partially zwitterionic NAA-modified oligonucleotides ...

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Scheme 6: Retrosynthetic summary of Ducho's and Grossmann's synthesis of fully cationic NAA-modified oligonuc...

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Published 04 Jun 2018

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